Experimental results show that C4-C14 bond of cyclopentadiene-menadione adduct is weakened by the steric effect of its angular methyl group through the crystal structural analysis. Consequently, the retro-Diels-Alder tendency of the adduct is enhanced at 130 ℃ through thermal analysis ( TG-DSC). 晶体结构分析显示环戊二烯-甲萘醌加合物的C4-C14键被它的角甲基空间效应所弱化,热分析(TG-DSC)研究显示在130℃该加合物的逆Diels-Alder反应趋势得到加强。